What's interesting about the LocalSettings date Container is that it can contain sub containers, so for example you could have multiple containers in the LocalSettings container that all have the same sub valuekey pairs, what i mean is you could have something like the following
- PersonOne
 - FirstName
 - LastName
 - BirthDate
 - PersonTwo
 - FirstName
 - LastName
 - BirthDate
 - PersonThree
 - FirstName
 - LastName
 - BirthDate
 - etc
 
ok lets look at an example
pretty straight forward app, now let's look at the xaml to make this happen
<Page
    x:Class="pc.LocalSettings.MainPage"
    xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
    xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
    xmlns:local="using:pc.LocalSettings"
    xmlns:d="http://schemas.microsoft.com/expression/blend/2008"
    xmlns:mc="http://schemas.openxmlformats.org/markup-compatibility/2006"
    mc:Ignorable="d">
   
<Page.Resources>
        <Style TargetType="TextBox">
            <Setter Property="FontSize" Value="34"/>
        </Style>
        <Style TargetType="ComboBox">
            <Setter Property="FontSize" Value="34"/>
        </Style>
        <Style TargetType="DatePicker">
            <Setter Property="FontSize" Value="34"/>
        </Style>
        <Style TargetType="Button">
            <Setter Property="FontSize" Value="34"/>
            <Setter Property="Margin" Value="0 20 20 0"/>
        </Style>
    </Page.Resources>
    <Grid Background="{ThemeResource ApplicationPageBackgroundThemeBrush}">
        <Grid.RowDefinitions>
            <RowDefinition Height="100"/>
            <RowDefinition Height="*"/>
        </Grid.RowDefinitions>
        <Grid.ColumnDefinitions>
            <ColumnDefinition Width="100"/>
            <ColumnDefinition Width="*"/>
        </Grid.ColumnDefinitions>
        <TextBlock Grid.Column="1" Text="LocalSettings Example" 
                   Style="{ThemeResource HeaderTextBlockStyle}" 
                   VerticalAlignment="Center"/>
        <StackPanel Grid.Column="1" Grid.Row="1" Margin="0 0 100 0">
            <ComboBox x:Name="People_CB"/>
            <TextBox x:Name="FirstName_TXT"
Header="First Name:"/>
            <TextBox x:Name="LastName_TXT"
Header="Last Name:"/>
            <DatePicker x:Name="BirthDate_DP"
Header="Date Picker:" />
            <StackPanel Orientation="Horizontal">
                <Button x:Name="Save_BTN" Content="Save"/>
                <Button x:Name="Delete_BTN" Content="Delete"/>
            </StackPanel>
        </StackPanel>
    </Grid>
</Page>
using System;
using System.Collections.Generic;
using Windows.Storage;
using Windows.UI.Xaml;
using Windows.UI.Xaml.Controls;
namespace pc.LocalSettings
{
    public sealed partial class MainPage : Page
    {
        public MainPage()
        {
            this.InitializeComponent();
            //Get
the local settings
            var localSettings = ApplicationData.Current.LocalSettings;
            //use
the key of each of the containers as an item
            //in our
people combo box
            foreach (var fullName in localSettings.Containers.Keys)
                this.People_CB.Items.Add(fullName);
            //add
our event revievers
            this.People_CB.SelectionChanged += People_CB_SelectionChanged;
            this.Save_BTN.Click += Save_BTN_Click;
            this.Delete_BTN.Click += Delete_BTN_Click;
        }
        //delete
a contianer from our local settings
        void Delete_BTN_Click(object sender, RoutedEventArgs e)
        {
            //get
the key name from the combo box
            var selectedPerson = People_CB.SelectedValue.ToString();
            //get
our local settings container
            var localSettings = ApplicationData.Current.LocalSettings;
            //delete
the container with the specified key
           
localSettings.DeleteContainer(selectedPerson);
            //remove
the corresponding key from the combo box
           
People_CB.Items.Remove(selectedPerson);
            //clear
the input values
            this.FirstName_TXT.Text = this.LastName_TXT.Text = String.Empty;
            this.BirthDate_DP.Date = DateTimeOffset.Now;
        }
        //load
the data for a specific container
        void People_CB_SelectionChanged(object sender, SelectionChangedEventArgs e)
        {
            //prevent
error when deleting a container
            if (e.AddedItems.Count == 0)
                return;
            //get
contaier key to load
            var selectedPerson = e.AddedItems[0].ToString();
            //get
local settings
            var localSettings = ApplicationData.Current.LocalSettings;
            //load
sub container with specified key
            ApplicationDataContainer Person = localSettings.Containers[selectedPerson];
            //populate
inputs with specified container values
            this.FirstName_TXT.Text = Person.Values["firstName"].ToString();
            this.LastName_TXT.Text = Person.Values["lastName"].ToString();
            this.BirthDate_DP.Date = (DateTimeOffset)Person.Values["birthDate"];
        }
        void Save_BTN_Click(object sender, RoutedEventArgs e)
        {
            //get
values from input fields
            var firstName = FirstName_TXT.Text;
            var lastName = LastName_TXT.Text;
            var birthDate = BirthDate_DP.Date;
            //set
key to use 
            var fullName = String.Format("{0}
{1}", firstName, lastName);
            //get
local settings
            var localSettings = ApplicationData.Current.LocalSettings;
            //get or
create the specified subcontaier
            ApplicationDataContainer Person = 
               
localSettings.CreateContainer(firstName, ApplicationDataCreateDisposition.Always);
            //save
or update the subcontainers values
            SaveContainerData(Person, "firstName",
firstName);
            SaveContainerData(Person, "lastName",
lastName);
            SaveContainerData(Person, "birthDate",
birthDate);
            if (!this.People_CB.Items.Contains(firstName))
                this.People_CB.Items.Add(firstName);
        }
        void SaveContainerData<T>(ApplicationDataContainer Container, string Key, T Value) {
            //check
if contaier already has key, if so update it if not create it.
            if (Container.Values.ContainsKey(Key))
                Container.Values[Key] = Value;
            else
                Container.Values.Add(new KeyValuePair<string, object>(Key, Value));
        }
    }
}
ApplicationDataContainer Person = localSettings.CreateContainer(firstName,
ApplicationDataCreateDisposition.Always);
Always:loads the container if it exists or creates it if it doesn't
Existing:only loads contains that exist throws and exception if you try to create a new one.
